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Current trends and challenges in the synthesis and applications of chitosan-based nanocomposites for plants: A review.
Yu, J, Wang, D, Geetha, N, Khawar, KM, Jogaiah, S, Mujtaba, M
Carbohydrate polymers. 2021;:117904
Abstract
Chitosan, a low-cost and multipurpose polymer with numerous desired physicochemical and biological properties has been tested for various applications in agriculture, pharmacy, and biomedicine industries. The availability of functional groups along the backbone makes chitosan readily available for other polymers and metal ions to form bio-nanocomposites. Different types of chitosan-based nanocomposites have been designed and tested for the enhancement of chitosan efficiency and ultimately widening the application areas of chitosan in plants. These nanocomposites serve different purposes such as eliciting plant's defence systems against different threats (pathogen attack), antimicrobial agent against bacteria, fungi and viruses, enhancement of nutrient uptake by plants, control release of micro/macronutrients, fungicides and herbicides. In this review, an extensive outlook has been provided (mainly in the last five years) to recent trends and advances in the fabrication and application of chitosan-based composites. Finally, current challenges and future development opportunities of chitosan-based nanocomposites for plants are discussed.
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2.
Sustainable Agriculture Systems in Vegetable Production Using Chitin and Chitosan as Plant Biostimulants.
Shahrajabian, MH, Chaski, C, Polyzos, N, Tzortzakis, N, Petropoulos, SA
Biomolecules. 2021;(6)
Abstract
Chitin and chitosan are natural compounds that are biodegradable and nontoxic and have gained noticeable attention due to their effective contribution to increased yield and agro-environmental sustainability. Several effects have been reported for chitosan application in plants. Particularly, it can be used in plant defense systems against biological and environmental stress conditions and as a plant growth promoter-it can increase stomatal conductance and reduce transpiration or be applied as a coating material in seeds. Moreover, it can be effective in promoting chitinolytic microorganisms and prolonging storage life through post-harvest treatments, or benefit nutrient delivery to plants since it may prevent leaching and improve slow release of nutrients in fertilizers. Finally, it can remediate polluted soils through the removal of cationic and anionic heavy metals and the improvement of soil properties. On the other hand, chitin also has many beneficial effects such as plant growth promotion, improved plant nutrition and ability to modulate and improve plants' resistance to abiotic and biotic stressors. The present review presents a literature overview regarding the effects of chitin, chitosan and derivatives on horticultural crops, highlighting their important role in modern sustainable crop production; the main limitations as well as the future prospects of applications of this particular biostimulant category are also presented.
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3.
Multifunctional Role of Chitosan Edible Coatings on Antioxidant Systems in Fruit Crops: A Review.
Adiletta, G, Di Matteo, M, Petriccione, M
International journal of molecular sciences. 2021;(5)
Abstract
Chitosan-based edible coatings represent an eco-friendly and biologically safe preservative tool to reduce qualitative decay of fresh and ready-to-eat fruits during post-harvest life due to their lack of toxicity, biodegradability, film-forming properties, and antimicrobial actions. Chitosan-based coatings modulate or control oxidative stress maintaining in different manner the appropriate balance of reactive oxygen species (ROS) in fruit cells, by the interplay of pathways and enzymes involved in ROS production and the scavenging mechanisms which essentially constitute the basic ROS cycle. This review is carried out with the aim to provide comprehensive and updated over-view of the state of the art related to the effects of chitosan-based edible coatings on anti-oxidant systems, enzymatic and non-enzymatic, evaluating the induced oxidative damages during storage in whole and ready-to-eat fruits. All these aspects are broadly reviewed in this review, with particular emphasis on the literature published during the last five years.
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4.
Applications of chitosan and chitosan based metallic nanoparticles in agrosciences-A review.
Chouhan, D, Mandal, P
International journal of biological macromolecules. 2021;:1554-1569
Abstract
The second most abundant biological macromolecule, next to cellulose is Chitosan. It is a versatile naturally occurring hydrophilic polysaccharide, derived as a deacetylated form of chitin. Due to its biocompatibility, biodegradability and antimicrobial activity, it has become a significant area of research towards drug delivery system, plant growth promotion, anti-pathogenic potentiality, seed priming and in plant defense mechanism. Various synthetic strategies have been established in recent years that couples different metals with chitosan nanoparticles. Metals like silver, copper, zinc, iron and nickel are highly compatible to form chitosan metallic nanoparticles and are proved to be non-toxic to the agricultural plant system. This review highlights the mode of action of nanochitosan on Gram-positive and Gram-negative bacteria in a distinguished manner as well as its action on fungi. A prime focus has been given on the skeletal framework of the metallic nanochitosan particles. Our study also projects the antimicrobial mechanism of chitosan based on its physiochemical properties, environmental factors and the type of organism on which it acts. Moreover, the mechanism for stimulation of plant immunity by metallic nanochitosan has also been reviewed. Our study relies on the conclusion that chitosan metallic nanoparticles showed enhanced anti-pathogenic and plant growth promoting activity in comparison to bulk chitosan.
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5.
Recent progress in preparation and applications of chitosan/calcium phosphate composite materials.
Salama, A
International journal of biological macromolecules. 2021;:240-252
Abstract
Studying the development of unique materials from sustainable and renewable resources has gained increasing concern due to the depletion of fossil resources. Chitosan and its derivatives have been considered as versatile candidates for preparing attractive materials. The fabrication of chitosan/calcium phosphate composite compounds has received much attention for the development of numerous promising products in different fields. In this short review, recent preparation strategies for chitosan/calcium phosphate composites such as freeze casting, vacuum-assisted filtration, and biomimetic mineralization were discussed. The review presented their advances for diverse applications such as bone tissue engineering implants, drug delivery, wound healing, dental caries, as well adsorption of organic and heavy metals from polluted water. The challenges and future perspectives for the application of chitosan/calcium phosphate materials in biomedical and environmental applications were also involved in this review article.
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6.
Fabrication and applications of bioactive chitosan-based organic-inorganic hybrid materials: A review.
Liu, X, Wu, Y, Zhao, X, Wang, Z
Carbohydrate polymers. 2021;:118179
Abstract
Organic-inorganic hybrid materials like bone, shells, and teeth can be found in nature, which are usually composed of biomacromolecules and nanoscale inorganic ingredients. Synergy of organic-inorganic components in hybrid materials render them outstanding and versatile performance. Chitosan is commonly used organic materials in bionic hybrid materials since its bioactive properties and could be controllable tailored by various means to meet complex conditions in different applications. Among these fabrication means, hybridization was favored for its convenience and efficiency. This review discusses three kinds of chitosan-based hybrid materials: hybridized with hydroxyapatite, calcium carbonate, and clay respectively, which are the representative of phosphate, carbonate, and hydrous aluminosilicates. Here, we reported the latest developments of the preparation methods, composition, structure and applications of these bioactive hybrid materials, especially in the biomedical field. Despite the great progress was made in bioactive organic-inorganic hybrid materials based on chitosan, some challenges and specific directions are still proposed for future development in this review.
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7.
Chitosan: A compound for drug delivery system in gastric cancer-a review.
Shafabakhsh, R, Yousefi, B, Asemi, Z, Nikfar, B, Mansournia, MA, Hallajzadeh, J
Carbohydrate polymers. 2020;:116403
Abstract
Gastric cancer is known as the fourth most common cancer and the second main cause of cancer-related deaths. Gastric cancer has some characteristics including high incidence rates of metastasis and mortality as well as low rates of early diagnosis, radical resection and 5-year survival. Radical surgery and following chemotherapy has been done for patients with early gastric cancer leading to 90 % survival rate in 5-year after operation. Besides, in advanced stage some cases don't have the chance of surgery as well as the risk of metastasis is high in these patients overally leading to poor prognosis. In recent years, finding a suitable drug delivery system for chemotherapeutic drugs in gastric cancer is an considerable subject for researchers. Chitosan is known as an appropriate compound for chemo-drug delivery in cancer treatment due to its high biodegradability and biocompatibility. Moreover, trans-mucosal drug delivery is facilitated by chitosan via its mucoadhesive and cationic features enhancing interaction with mucous membrane. In addition, a large amount of experimental evidence has reported the efficacy of chitosan for drug delivery in gastric cancer. Thus, the aim of this article was to review this evidence as well as new chitosan-based drug delivery systems investigated in gastric cancer.
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8.
Review of Chitosan-Based Polymers as Proton Exchange Membranes and Roles of Chitosan-Supported Ionic Liquids.
Rosli, NAH, Loh, KS, Wong, WY, Yunus, RM, Lee, TK, Ahmad, A, Chong, ST
International journal of molecular sciences. 2020;(2)
Abstract
Perfluorosulphonic acid-based membranes such as Nafion are widely used in fuel cell applications. However, these membranes have several drawbacks, including high expense, non-eco-friendliness, and low proton conductivity under anhydrous conditions. Biopolymer-based membranes, such as chitosan (CS), cellulose, and carrageenan, are popular. They have been introduced and are being studied as alternative materials for enhancing fuel cell performance, because they are environmentally friendly and economical. Modifications that will enhance the proton conductivity of biopolymer-based membranes have been performed. Ionic liquids, which are good electrolytes, are studied for their potential to improve the ionic conductivity and thermal stability of fuel cell applications. This review summarizes the development and evolution of CS biopolymer-based membranes and ionic liquids in fuel cell applications over the past decade. It also focuses on the improved performances of fuel cell applications using biopolymer-based membranes and ionic liquids as promising clean energy.
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9.
Research advances in preparation and application of chitosan nanofluorescent probes.
Liu, P, Wang, R, Su, W, Qian, C, Li, X, Gao, L, Jiao, T
International journal of biological macromolecules. 2020;:1884-1896
Abstract
Nanofluorescent material is developing rapidly as a new type of material. Nanofluorescent probes have broad application prospects in biological analysis, drug metabolism, and semiconductor optical materials. Chitosan is non-toxic and rich in nature which has good biocompatibility, and it can be combined with fluorescent probes. Therefore, the preparation and application of Nanofluorescent probes using chitosan as a carrier is summarized in this article. Fluorescent probes can be combined with other different materials through different reaction mechanisms, and the prepared composite materials can be widely used in biomaterials, sewage treatment, medicine and other fields.
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10.
Chitosan-Based Agronanochemicals as a Sustainable Alternative in Crop Protection.
Maluin, FN, Hussein, MZ
Molecules (Basel, Switzerland). 2020;(7)
Abstract
The rise in the World's food demand in line with the increase of the global population has resulted in calls for more research on the production of sustainable food and sustainable agriculture. A natural biopolymer, chitosan, coupled with nanotechnology could offer a sustainable alternative to the use of conventional agrochemicals towards a safer agriculture industry. Here, we review the potential of chitosan-based agronanochemicals as a sustainable alternative in crop protection against pests, diseases as well as plant growth promoters. Such effort offers better alternatives: (1) the existing agricultural active ingredients can be encapsulated into chitosan nanocarriers for the formation of potent biocides against plant pathogens and pests; (2) the controlled release properties and high bioavailability of the nanoformulations help in minimizing the wastage and leaching of the agrochemicals' active ingredients; (3) the small size, in the nanometer regime, enhances the penetration on the plant cell wall and cuticle, which in turn increases the argochemical uptake; (4) the encapsulation of agrochemicals in chitosan nanocarriers shields the toxic effect of the free agrochemicals on the plant, cells and DNA, thus, minimizing the negative impacts of agrochemical active ingredients on human health and environmental wellness. In addition, this article also briefly reviews the mechanism of action of chitosan against pathogens and the elicitations of plant immunity and defense response activities of chitosan-treated plants.