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1.
Ozonation of 47 organic micropollutants in secondary treated municipal effluents: Direct and indirect kinetic reaction rates and modelling.
Mathon, B, Coquery, M, Liu, Z, Penru, Y, Guillon, A, Esperanza, M, Miège, C, Choubert, JM
Chemosphere. 2021;:127969
Abstract
Micropollutants like pharmaceuticals, hormones and pesticides are still found in treated municipal wastewater. An effective way to degrade micropollutants is to use oxidants such as ozone or hydroxyl radicals. We designed an innovative experimental protocol combining batch experiments and a study of a full-scale WWTP to understand and predict the removal via ozonation of typical micropollutants present in secondary treated effluents. First, the direct and indirect ozonation of 47 organic micropollutants was scrutinized, then a model was developed and calibrated to simulate the ozone transfers and the oxidation of the selected micropollutants. The kinetic rate constants between micropollutants and ozone or hydroxyl radicals (OH●) were determined for 47 micropollutants found in secondary treated effluent. We classified the micropollutants into low- (kO3 between 1.50 and 4.47 × 102 L mol-1. s-1), medium- (kO3 between 1.31 × 103 and 4.92 × 103 L mol-1. s-1) and high-oxidizable groups (kO3 between 9.44 × 104 and 8.18 × 106 L mol-1. s-1) according to their reactivity with ozone, and identified the major degradation pathways for all 47 micropollutants. Micropolluants of the low- and medium-oxidizable groups were largely eliminated by the indirect pathway, at 96% and 84% on average, respectively. In contrast, micropollutants of high-oxidizable group were largely eliminated by the direct pathway, at 98% on average. The model successfully simulated the direct and indirect ozonation of the 47 micropollutants in batch experiments and confirmed the predominant pathways for each group. Finally, the model was applied to the full-scale ozonation process operated at an ozone dose ranging from 0.5 to 1.6 gO3. gDOC-1. The model was found to reliably simulate the ozonation-process removal efficiencies for 4 micropollutants (imidacloprid, fenofibric acid, metronidazole and ketoprofen).
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2.
Boron nitride-based materials for water purification: Progress and outlook.
Ihsanullah, I
Chemosphere. 2021;:127970
Abstract
Analogous to the carbon family, boron nitride (BN)-based materials have gained considerable attention in recent times for applications in various fields. Owing to their extraordinary characteristics, i.e., high surface area, low density, superior thermal stability, mechanical strength, and conductivity, excellent corrosion, and oxidation resistance, the BN nanomaterials have been explored in water remediation. This article critically evaluates the latest development in applications of BN-based materials in water purification with focus on adsorption, synthesis of novel membranes and photocatalytic degradation of pollutants. The adsorption of various noxious pollutants, i.e., dyes, organic compounds, antibiotics, and heavy metals from aqueous medium BN-based materials are described in detail by illustrating the adsorption mechanism and regeneration potential. The major hurdles and opportunities related to the synthesis and water purification applications of BN-based materials are underscored. Finally, a roadmap is suggested for future research to assure the effective applications of BN-based materials in water purification. This review is beneficial in understanding the current status of these unique materials in water purification and accelerating the research focusing their future water remediation applications.
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3.
Heterogeneous Fenton catalysts: A review of recent advances.
Thomas, N, Dionysiou, DD, Pillai, SC
Journal of hazardous materials. 2021;(Pt B):124082
Abstract
Heterogeneous Fenton catalysts are emerging as excellent materials for applications related to water purification. In this review, recent trends in the synthesis and application of heterogeneous Fenton catalysts for the abatement of organic pollutants and disinfection of microorganisms are discussed. It is noted that as the complexity of cell wall increases, the resistance level towards various disinfectants increases and it requires either harsh conditions or longer exposure time for the complete disinfection. In case of viruses, enveloped viruses (e.g. SARS-CoV-2) are found to be more susceptible to disinfectants than the non-enveloped viruses. The introduction of plasmonic materials with the Fenton catalysts broadens the visible light absorption efficiency of the hybrid material, and incorporation of semiconductor material improves the rate of regeneration of Fe(II) from Fe(III). A special emphasis is given to the use of Fenton catalysts for antibacterial applications. Composite materials of magnetite and ferrites remain a champion in this area because of their easy separation and reuse, owing to their magnetic properties. Iron minerals supported on clay materials, perovskites, carbon materials, zeolites and metal-organic frameworks (MOFs) dramatically increase the catalytic degradation rate of contaminants by providing high surface area, good mechanical stability, and improved electron transfer. Moreover, insights to the zero-valent iron and its capacity to remove a wide range of organic pollutants, heavy metals and bacterial contamination are also discussed. Real world applications and the role of natural organic matter are summarised. Parameter optimisation (e.g. light source, dosage of catalyst, concentration of H2O2 etc.), sustainable models for the reusability or recyclability of the catalyst and the theoretical understanding and mechanistic aspects of the photo-Fenton process are also explained. Additionally, this review summarises the opportunities and future directions of research in the heterogeneous Fenton catalysis.
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4.
Cyanobacterial blooms in wastewater treatment facilities: Significance and emerging monitoring strategies.
Romanis, CS, Pearson, LA, Neilan, BA
Journal of microbiological methods. 2021;:106123
Abstract
Municipal wastewater treatment facilities (WWTFs) are prone to the proliferation of cyanobacterial species which thrive in stable, nutrient-rich environments. Dense cyanobacterial blooms frequently disrupt treatment processes and the supply of recycled water due to their production of extracellular polymeric substances, which hinder microfiltration, and toxins, which pose a health risk to end-users. A variety of methods are employed by water utilities for the identification and monitoring of cyanobacteria and their toxins in WWTFs, including microscopy, flow cytometry, ELISA, chemoanalytical methods, and more recently, molecular methods. Here we review the literature on the occurrence and significance of cyanobacterial blooms in WWTFs and discuss the pros and cons of the various strategies for monitoring these potentially hazardous events. Particular focus is directed towards next-generation metagenomic sequencing technologies for the development of site-specific cyanobacterial bloom management strategies. Long-term multi-omic observations will enable the identification of indicator species and the development of site-specific bloom dynamics models for the mitigation and management of cyanobacterial blooms in WWTFs. While emerging metagenomic tools could potentially provide deep insight into the diversity and flux of problematic cyanobacterial species in these systems, they should be considered a complement to, rather than a replacement of, quantitative chemoanalytical approaches.
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5.
Biomedical Applications of Biomolecules Isolated from Methanotrophic Bacteria in Wastewater Treatment Systems.
Salem, R, ElDyasti, A, Audette, GF
Biomolecules. 2021;(8)
Abstract
Wastewater treatment plants and other remediation facilities serve important roles, both in public health, but also as dynamic research platforms for acquiring useful resources and biomolecules for various applications. An example of this is methanotrophic bacteria within anaerobic digestion processes in wastewater treatment plants. These bacteria are an important microbial source of many products including ectoine, polyhydroxyalkanoates, and methanobactins, which are invaluable to the fields of biotechnology and biomedicine. Here we provide an overview of the methanotrophs' unique metabolism and the biochemical pathways involved in biomolecule formation. We also discuss the potential biomedical applications of these biomolecules through creation of beneficial biocompatible products including vaccines, prosthetics, electronic devices, drug carriers, and heart stents. We highlight the links between molecular biology, public health, and environmental science in the advancement of biomedical research and industrial applications using methanotrophic bacteria in wastewater treatment systems.
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6.
Optimizing Adsorption of 17α-Ethinylestradiol from Water by Magnetic MXene Using Response Surface Methodology and Adsorption Kinetics, Isotherm, and Thermodynamics Studies.
Xu, M, Huang, C, Lu, J, Wu, Z, Zhu, X, Li, H, Xiao, L, Luo, Z
Molecules (Basel, Switzerland). 2021;(11)
Abstract
Magnetic MXene composite Fe3O4@Ti3C2 was successfully prepared and employed as 17α-ethinylestradiol (EE2) adsorbent from water solution. The response surface methodology was employed to investigate the interactive effects of adsorption parameters (adsorption time, pH of the solution, initial concentration, and the adsorbent dose) and optimize these parameters for obtaining maximum adsorption efficiency of EE2. The significance of independent variables and their interactions were tested by the analysis of variance (ANOVA) and t-test statistics. Optimization of the process variables for maximum adsorption of EE2 by Fe3O4@Ti3C2 was performed using the quadratic model. The model predicted maximum adsorption of 97.08% under the optimum conditions of the independent variables (adsorption time 6.7 h, pH of the solution 6.4, initial EE2 concentration 0.98 mg L-1, and the adsorbent dose 88.9 mg L-1) was very close to the experimental value (95.34%). pH showed the highest level of significance with the percent contribution (63.86%) as compared to other factors. The interactive influences of pH and initial concentration on EE2 adsorption efficiency were significant (p < 0.05). The goodness of fit of the model was checked by the coefficient of determination (R2) between the experimental and predicted values of the response variable. The response surface methodology successfully reflects the impact of various factors and optimized the process variables for EE2 adsorption. The kinetic adsorption data for EE2 fitted well with a pseudo-second-order model, while the equilibrium data followed Langmuir isotherms. Thermodynamic analysis indicated that the adsorption was a spontaneous and endothermic process. Therefore, Fe3O4@Ti3C2 composite present the outstanding capacity to be employed in the remediation of EE2 contaminated wastewaters.
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7.
One-pot fabrication of lignin-based aromatic porous polymers for efficient removal of bisphenol AF from water.
Sun, L, Chai, K, Zhou, L, Liao, D, Ji, H
International journal of biological macromolecules. 2021;:396-405
Abstract
To remove the bisphenol AF (BPAF) from aqueous solution, two different types of lignin-based aromatic porous polymers (LAPP-1 and LAPP-2) were fabricated via one-pot crosslinking of lignin with 1,4-dichloroxylene and 4,4'-bis(chloromethyl)-1,1'-biphenyl, respectively. The successful synthesis of LAPPs was confirmed by FTIR and XPS, SEM, TEM and N2 adsorption-desorption analysis. Then, batch adsorption experiments were conducted to investigate adsorption properties toward BPAF. Based on the results, the adsorption processes were in accordance with the pseudo-second-order kinetic model and the Freundlich isotherm model, and the thermodynamic studies showed that the adsorption was a spontaneous and exothermic process. It is remarkable that LAPPs exhibited good adsorption performance in wide ranges of pH and ionic strength as well as in recycling process. Notably, compared to LAPP-1, LAPP-2 exhibited higher adsorption capacity for BPAF, which can be ascribed to its higher porosity and content of aromatic ring. Moreover, the comprehensive analysis of experimental and theoretical results indicated that the π-π interactions and pore adsorption may jointly drive the uptake process of BPAF. Considering the simple fabrication method employed and excellent BPAF adsorption performance, LAPPs provided new insights into the development of advanced lignin-based adsorbents for removal of BPAF from water.
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8.
Adsorption of 17β-estradiol from aqueous solution by raw and direct/pre/post-KOH treated lotus seedpod biochar.
Liu, N, Liu, Y, Zeng, G, Gong, J, Tan, X, JunWen, , Liu, S, Jiang, L, Li, M, Yin, Z
Journal of environmental sciences (China). 2020;:10-23
Abstract
Five biochars derived from lotus seedpod (LSP) were applied to examine and compare the adsorption capacity of 17β-estradiol (E2) from aqueous solution. The effect of KOH activation and the order of activation steps on material properties were discussed. The effect of contact time, initial concentration, pH, ionic strength and humic acid on E2 adsorption were investigated in a batch adsorption process. Experimental results demonstrated that the pseudo second-order model fitted the experimental data best and that adsorption equilibrium was reached within 20 hr. The efficiency of E2 removal increased with increasing E2 concentration and decreased with the increase of ionic strength. E2 adsorption on LSP-derived biochar (BCs) was influenced little by humic acid, and slightly affected by the solution pH when its value ranged from 4.0 to 9.0, but considerably affected at pH 10.0. Low environmental temperature is favorable for E2 adsorption. Chemisorption, π-π interactions, monolayer adsorption and electrostatic interaction are the possible adsorption mechanisms. Comparative studies indicated that KOH activation and the order of activation steps had significant impacts on the material. Post-treated biochar exhibited better adsorption capacity for E2 than direct treated, pre-treated, and raw LSP biochar. Pyrolyzed biochar at higher temperature improved E2 removal. The excellent performance of BCs in removing E2 suggested that BCs have potential in E2 treatment and that the biochar directly treated by KOH would be a good choice for the treatment of E2 in aqueous solution, with its advantages of good efficiency and simple technology.
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9.
Water Treatment: Are Membranes the Panacea?
Landsman, MR, Sujanani, R, Brodfuehrer, SH, Cooper, CM, Darr, AG, Davis, RJ, Kim, K, Kum, S, Nalley, LK, Nomaan, SM, et al
Annual review of chemical and biomolecular engineering. 2020;:559-585
Abstract
Alongside the rising global water demand, continued stress on current water supplies has sparked interest in using nontraditional source waters for energy, agriculture, industry, and domestic needs. Membrane technologies have emerged as one of the most promising approaches to achieve water security, but implementation of membrane processes for increasingly complex waters remains a challenge. The technical feasibility of membrane processes replacing conventional treatment of alternative water supplies (e.g., wastewater, seawater, and produced water) is considered in the context of typical and emerging water quality goals. This review considers the effectiveness of current technologies (both conventional and membrane based), as well as the potential for recent advancements in membrane research to achieve these water quality goals. We envision the future of water treatment to integrate advanced membranes (e.g., mixed-matrix membranes, block copolymers) into smart treatment trains that achieve several goals, including fit-for-purpose water generation, resource recovery, and energy conservation.
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10.
Microbial assisted phytodepuration for water reclamation: Environmental benefits and threats.
Riva, V, Riva, F, Vergani, L, Crotti, E, Borin, S, Mapelli, F
Chemosphere. 2020;:124843
Abstract
Climate changes push for water reuse as a priority to counteract water scarcity and minimize water footprint especially in agriculture, one of the highest water consuming human activities. Phytodepuration is indicated as a promising technology for water reclamation, also in the light of its economic and ecological sustainability, and the use of specific bacterial inocula for microbial assisted phytodepuration has been proposed as a further advance for its implementation. Here we provided an overview on the selection and use of plant growth promoting bacteria in Constructed Wetland (CW) systems, showing their advantages in terms of plant growth support and pollutant degradation abilities. Moreover, CWs are also proposed for the removal of emerging organic pollutants like antibiotics from urban wastewaters. We focused on this issue, still debated in the literature, revealing the necessity to deepen the knowledge on the antibiotic resistance spread into the environment in relation to treated wastewater release and reuse. In addition, given the presence in the plant system of microhabitats (e.g. rhizosphere) that are hot spot for Horizontal Gene Transfer, we highlighted the importance of gene exchange to understand if these events can promote the diffusion of antibiotic resistance genes and antibiotic resistant bacteria, possibly entering in the food production chain when treated wastewater is used for irrigation. Ideally, this new knowledge will lead to improve the design of phytodepuration systems to maximize the quality and safety of the treated effluents in compliance with the 'One Health' concept.